Technically with the right engineering you could connect 2
monohull boats together. The biggest issue will be the large forces, vertical, horizontal, twisting etc. on the structure connecting the hulls.
Then you would need to decide whether to run two masts or eliminate the masts from the monos and make a
mast step on the connecting structure. The forces on the
mast will now have to be engineered to survive.
Then you have to decide if you are going to have a
deck house between the hulls or not. One of the attractions of the cruising catamaran is the large deckhouse/salon. This structure now has to be engineered and the additional forces have to be engineered into the structure that connects the hulls.
At the time of design,
layup and building all of this engineering is integrated and planned together. That allows the structure to be lighter than if everything is done after the fact as an "add on."
When you are done you will have a catamaran that is heavier than others for the
LOA with a deeper
draft unless you have done the
work and engineering to redesign or remove the keels from the original hulls.
When you consider the cost of all this work and material you might be better off with a bigger mono or a purpose built cat.