I have seizing problems all the time with SS screws used in aluminum parts. The screws attaching the stanchions to the toe rail were the worst you can imagine.
Sometimes the combination of heat, impact, aero kroil, and patience works, and too often it doesn't or I just run out of time and patience.
So I break out the drill and tap and die set. Being a european
boat I have tap and die kits for SAE and metric. This is much faster and easier than the above strategies and I am now much less willing to struggle with a fused screw and less scared of not being able to get it out than before.
On occasion I've drilled it out and the hole is too big for the original size screw, so I either move up a size or install a helicoil.
Then, when installing the new screw, if the metals are dissimilar or not, I use Tef-Gel to prevent galling and future fusion problems.
I find it empowering to be able to do this pro-level stuff and it isn't hard after you have the right tools and have done it once.