I'm having a very difficult time understanding the photos, but my impression is first, they are
bronze, and second,
salt water has gotten to the outsides of them, eiher by leaky mounts or (more likely) by
leaks from unsealed conical center sections. I'm betting they haven't been closed in many years. The green corrosion is copper oxide.
So, a reasonable aopproach, should you want to take it on, would be to unmount the valves, disassemble them, with some difficulty I suspect, and see if they can be restored. If not, go with Marelon
replacements.