What is Biodiesel?
Biodiesel is a diesel replacement fuel that is manufactured from vegetable oils, recycled
cooking greases or oils, or animal fats. Because plants produce oils from sunlight and air,
and can do so year after year on cropland, these oils are renewable. Animal fats are
produced when the animal consumes plant oils and other fats, and they too are renewable.
Used
cooking oils are mostly made from vegetable oils, but may also contain animal fats.
Used cooking oils are both recycled and renewable.
The biodiesel manufacturing process converts oils and fats into chemicals called long
chain mono alkyl esters, or biodiesel. These chemicals are also referred to as fatty acid
methyl esters or FAME. In the manufacturing process, 100 pounds of oils or fats are
reacted with 10 pounds of a short chain alcohol (usually methanol) in the presence of a
catalyst (usually sodium or potassium hydroxide) to form 100 pounds of biodiesel and 10
pounds of glycerine. Glycerine is a sugar, and is a co-product of the biodiesel process.
Raw or refined vegetable
oil, or recycled greases that have not been processed into
biodiesel, are not biodiesel and should be avoided.
Research shows that vegetable
oil
or greases used in CI engines at levels as low as 10% to 20%, can cause long-term engine
deposits, ring sticking, lube oil gelling, and other
maintenance problems and can reduce
engine life. These problems are caused mostly by the greater viscosity, or thickness, of
the raw oils (around 40 mm2/s) compared to that of the diesel fuel for which the engines
and injectors were designed (between 1.3 and 4.1 mm2/s). To avoid viscosity-related
problems, vegetable oils and other feedstocks are converted into biodiesel. Through the
process of converting vegetable oil or greases to biodiesel, we reduce viscosity of the fuel
to values similar to conventional diesel fuel ( biodiesel values are typically between 4 and
5 mm2/s).
ASTM International is a consensus based standards group comprised of engine and fuel
injection
equipment companies, fuel producers, and fuel users whose standards are
recognized in the United States by most
government entities, including states with the
responsibility of insuring fuel quality. The specification for biodiesel (B100) is ASTM
D6751-03. This specification is intended to insure the quality of biodiesel to be used as a
blend stock at 20% and lower blend levels. Any biodiesel used in the United States for
blending should meet ASTM D6751 standards.
The definition of biodiesel within ASTM D6751 describes long chain fatty acid esters
from vegetable or animal fats that contain only one alcohol molecule on one ester
linkage. Raw or refined vegetable oils contain three ester linkages and are therefore not
legally biodiesel. Biodiesel can be made from methyl, ethyl, isopropyl, and otheralcohols, but most biodiesel
research focuses on methyl esters and virtually all
commercial-production in the United States today uses methyl esters. Some research has
occurred on ethyl esters (biodiesel produced with ethanol as the alcohol rather than
methanol), however higher ethanol prices relative to methanol, lower ethyl ester
conversions, and the difficulty of recycling excess ethanol internally in the process, have
hampered ethyl ester production in the
commercial marketplace. Therefore, in this
document we will only consider methyl esters.
Biodiesel is a legally registered fuel and fuel additive with the U.S. Environmental
Protection Agency (EPA). The EPA
registration includes all biodiesel meeting the ASTM
International biodiesel specification, ASTM D 6751, and is not dependent upon the oil or
fat used to produce the biodiesel or the specific process employed.
Do not be fooled by other so-called “biofuel” products, many of which are being offered
to consumers without the benefit of EPA
registration or extensive testing and
demonstrations. In fact, if you
purchase methyl ester that does not meet ASTM biodiesel
standards, it is not legally biodiesel and should not be used in diesel engines or other
equipment designed to operate on diesel fuel. Methyl esters are used as an industrial
lubricant and solvent in some applications so be sure to
purchase only ASTM grade
methyl esters (i.e. biodiesel).
Biodiesel is a recognized alternative fuel under the Energy Policy Act of 1992 (EPAct) as
amended in 1996. EPAct requires that over 75% of new vehicle purchases by certain
federal, state, and alternative fuel provider fleets be alternative fueled vehicles. As a
recognized alternative fuel, any vehicle certified to run on B100 could qualify under the
alternative fuel vehicle purchase provisions of EPAct, but it does not appear that any
vehicles meeting this requirement are available today. B100 is more expensive than other
alternative fuel options, and the original equipment manufacturer (OEM) community has
had little interest in certifying vehicles on B100, so this vehicle credit has not created a
market for biodiesel.
EPAct was amended in 1998 by the Energy Conservation and Reauthorization Act
(ECRA). The amendment allowed qualified fleets to use B20 in existing vehicles to
generate alternative fuel vehicle purchase credits, with some limitations. This has created
significant B20 use by
government and alternative fuel provider fleets. For more
information on using biodiesel to fulfill EPAct requirements, see Chapter 8, Using
Biodiesel Under the Energy Policy Act.
As biodiesel grows in popularity, some states are beginning to develop biodiesel
incentive policies to promote biodiesel use and production. State policies can change
rapidly, so please contact your state agencies or the National Biodiesel Board for more
information.
Biodiesel Displaces Imported Petroleum
The fossil fuel energy required to produce biodiesel from soybean oil is only a fraction
(31%) of the energy contained in one gallon of the fuel.2 You get 3.2 units of fuel energy
from biodiesel for every unit of fossil energy used to produce the fuel. That estimate
includes the energy used in diesel farm equipment and transportation equipment (trucks,
locomotives), fossil fuels used to produce fertilizers and pesticides, fossil fuels used to
produce steam and electricity, and methanol used in the manufacturing process. Because
biodiesel is an energy-efficient fuel, it can extend petroleum supplies and makes for
sound state or federal energy policy.
Biodiesel Reduces Emissions
When biodiesel displaces petroleum, it reduces global warming gas emissions such as
carbon dioxide (CO2). When plants like soybeans grow they take CO2 from the air to
make the stems, roots, leaves, and seeds (soybeans). After the oil is extracted from the
soybeans, it is converted into biodiesel and when burned produces CO2 and other
emissions, which return to the atmosphere. This cycle does not add to the net CO2
concentration in the air because the next soybean crop will reuse the CO2 in order to
grow.
When fossil fuels are burned, however, 100% of the CO2 released adds to the CO2
concentration levels in the air. Because fossil fuels are used to produce biodiesel, the
recycling of CO2 with biodiesel is not 100%, but substituting biodiesel for petroleum
diesel reduces life-cycle CO2 emissions by 78%. B20 reduces CO2 by 15.66%.3
Biodiesel reduces tailpipe particulate matter (PM), hydrocarbon (HC), and carbon
monoxide (CO) emissions from most modern four-stroke CI engines. These benefits
occur because the fuel (B100) contains 11% oxygen by weight. The presence of fuel
oxygen allows the fuel to burn more completely, so fewer unburned fuel emissions result.
This same phenomenon reduces air toxics, because the air toxics are associated with the
unburned or partially burned HC and PM emissions. Testing has shown that PM, HC, and
CO reductions are independent of the feedstock used to make biodiesel. The EPA
reviewed 80 biodiesel emission tests on CI engines and has concluded that the benefits
are real and predictable over a wide range of biodiesel blends (Figure 1, page 5).4
3.7 B100 Microbial Contamination
Biocides are recommended for conventional and biodiesel fuels wherever biological
growth in the fuel has been a problem. If biological contamination is a problem, water
contamination needs to be controlled since the aerobic fungus, bacteria, and yeast
hydrocarbon utilizing microorganisms (HUMBUGS) usually grow at the fuel-water
interface. Anaerobic colonies, usually sulfur reducing, can be active in sediments on tank
surfaces and cause
corrosion. Since the biocides
work where the HUMBUGS live (in the
water), products that are used with diesel fuels will
work equally well with biodiesel.
You can get the full document at this link.........................._/)
http://www.nrel.gov/vehiclesandfuels...fs/tp36182.pdf