If you are going to have
a\ the alt
b\ the
solar
and
2
battery banks
Then I would make the alt charge BOTH banks (does not have to be at the same time, a switch will do as the most basic solution).
And I would make the solar charge BOTH banks (again, does not have to be automated or concurrent, but to do have this capacity, a basic switch, again, will do).
Given $ or $$ you can automate the process and add some monitoring too.
However, if you sail mostly close to docks, you may just wire one thing to one bank and then upcharge while at the
dock - for from my experience shore based chargers are cheaper than alternator and solar regulators for mixed and advance batt banks.
BTW I would keep the battery banks SAME chemistry. If your home bank is Lith, make the starter bank Lith too. Or simply start the
engine from the house bank. Then you can either forego the 2nd bank or else have a smaller bank as a "reserve". Still, I would not mix the chemisties - have one kind again simplifies the
gear attached to charge everything.
ymmv
b.