Thanks all for the options, fellas.
I did geo-reference the PDFs in a number of ways but struggled to get them perfectly calibrated.
It appears that the WA DoT did release geo-referenced digital charts at one time but, on enquiry, they stated this was no longer a provided service.
So, I then used SASPlanet to capture the Navionics charts from the Navionics website, as suggested by sailorF54. Thank you! Running SASP within GE2KAP they saved as geo-referenced kaps.
Where the WA DoT large-scale charts gave good detail then that appears in the Navionics charts. Presumably they have incorporated the WA
survey data. And, geo-referencing the Navionics charts around Hillarys
Boat Harbour against
Google Earth and ArcGIS - the calibration appears perfect.
Better than my attempts at geo-referencing. And, a lot less pains-taking.