I'd do something else first...
Rarely is there a blockage in the vent LINE...The two most common locations for a vent blockage are the vent thru-hull and the other end of the vent line--that end of the hose and the vent fitting on the tank. So I'd start by
cleaning out the thru-hull...use a screwdriver blade, ice pick, knock out any screen--whatever works. If that doesn't result in a spew out the vent, you'll need to relieve the pressure before removing the vent line from the tank to clean that end out...so open the
deck pumpout fitting VERY CAREFULLY with a hose at the ready. Be sure you're UPwind of it! Scrape out that end of the vent line and the vent fitting on the tank...reconnect the vent line.
If there's a filter in the vent line, remove it...once a filter gets wet--which can happen when a tank is overfilled or even due to heeling--the charcoal swells and blocks the vent...one of the reasons why vent filters aren't recommended for use on most sailboats.
To prevent future vent blockages, replace the "vent" thru-hull with an open bulkhead aka "mushroom" fitting--the kind your
bilge pump use. This will not only vastly improve the air exchange needed to prevent
odor from forming in the tank, but it'll also let you put a hose nozzle against it to backflush the vent line every time you wash the
boat and/or pumpout or dump. Any that's trying to set up housing keeping in the vent line will get a
water slide ride into the tank and prevent buildup in the other end of the vent line.
--Peggie